| 2 Arsenic removal by inorganic ion-exchanger | |
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Hirotaka Amimono |
UNITIKA ENVIRONMENTAL |
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1. Introduction
The method of arsenic removal is divided roughly based on the following three principles: (1) the coagulation-sedimentation method by iron salt or aluminum salt, (2) the adsorption method by ion-exchange resin, chelating resin, activated alumina, or cerium agent, and (3) the separation method by reverse osmosis (RO). The processing of arsenic removal is composed of a single principle or a combination. The practical utilization of the remediation processes for arsenic removal needs to consider the following factors: (1) accuracy of removal, (2) ions for removal (As(III), As(VI)), and (3) the amount of the generated sludge. In this paper, a chelating resin, which functions with selectivity of ions, and synthetic hydrotalcite (HT), which is one of the inorganic ion-exchangers, are described. 2. Chelating resin The use of the chelating resin, which supports zirconium on the resin, in arsenic removal is through the adsorption method. Although its mechanism is not clear, the adsorption ability increases parallel to the level of coexisting salinity, thereby, more accurate removal of arsenic is produced. Chelating resin is spherical and easy to handle. However, there is a challenge that the adsorption ability to As(III) is inferior. 3. Inorganic ion-exchanger The pertinent characteristic of HT, which is one of the clay minerals, is its function as a selective ion-exchanger. HT is a layered compound and it holds negative ions between the layers. The negative ions are exchanged with the negative ions in the medium, which are objects for adsorption. Generally, their chemical formulas are indicated as follows:
![]() Fig. 1 Arsenic adsorption isotherm by inorganic ion-exchanger (temperature 25℃, pH6?7, no NaCl mixed)
Table 1 Pros and cons on arsenic removal in water
(Chelating resin method and inorganic ion-exchange method) 4. Practical method of arsenic removal in water (2) Arsenic removal of certain industrial wastewater
![]() Fig. 2 Outline of processing flow on the effluent containing arsenic (Highlighted areas show additional equipment.)
Table 2 Running cost of arsenic removal in water
5. Conclusion | |
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